USGS Spectral Library
Researchers at the USGS Spectroscopy Laboratory have measured the spectral reflectance of thousands of materials in the lab and compiled them in the USGS Spectral Library. Detailed sample descriptions are provided with the spectra, including the results of X-ray Diffraction, Electron Probe Micro-Analysis, and other analytical methods.
Spectral Library Version 7 Data Series Report

Kokaly, R.F., Clark, R.N., Swayze, G.A., Livo, K.E., Hoefen, T.M., Pearson, N.C., Wise, R.A., Benzel, W.M., Lowers, H.A., Driscoll, R.L., and Klein, A.J., 2017, USGS Spectral Library Version 7: U.S. Geological Survey Data Series 1035, 61 p., https://doi.org/10.3133/ds1035.
Spectral Library Version 7 Data

Kokaly, R.F., Clark, R.N., Swayze, G.A., Livo, K.E., Hoefen, T.M., Pearson, N.C., Wise, R.A., Benzel, W.M., Lowers, H.A., Driscoll, R.L., and Klein, A.J., 2017, USGS Spectral Library Version 7 Data: U.S. Geological Survey data release, https://dx.doi.org/10.5066/F7RR1WDJ.